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有色金属(冶炼部分):2015,(7):8-12
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微波和等离子体辅助次氯酸钠浸出含砷铜矿脱砷工艺
赵卓英,齐越,杜冬云
(中南民族大学 环境科学与工程研究所,中南民族大学 环境科学与工程研究所,中南民族大学 环境科学与工程研究所)
Arsenic Removal from Arsenic-bearing Copper Ore by Sodium Hypochlorite Leaching Assisted with Microwave and Low-pressure Glow Discharge Plasma
ZHAO Zhuo-ying,QI Yue and DU Dong-yun
(Institute of Environment Engineering and Science,South Central University for Nationalities,,)
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投稿时间:2015-01-19     修订日期:2015-01-24     录用日期:2015-01-27     网络发布日期:2015-06-23
中文摘要: 采用次氯酸钠浸出方法降低含砷铜矿中的砷含量。最佳工艺条件为:温度30 ℃、粒度54~74 μm、NaClO浓度0.39 mol/L、NaOH用量为矿样的1.67%、时间90 min、液固比40︰1(mL/g),砷浸出率为47.53%。微波场和辉光放电等离子体场辅助次氯酸钠浸出,砷浸出率分别为66%、72.88%,处理后铜矿中砷含量分别降至0.15%、0.12%,均满足铜精矿二级品砷含量的指标要求。
Abstract:Arsenic content was reduced by leaching arsenic-bearing copper ore with sodium hypochlorite under alkaline oxidizing condition. The results show that arsenic leaching rate is 47.53% under the optimum conditions including temperature of 30 ℃, particle size of 54~74 μm, sodium hypochlorite concentration of 0.39 mol/L, sodium hydroxide dosage of 1.67% of sample ore, leaching time of 90 min, and ratio of liquid to solid of 40︰1(mL/g). Arsenic leaching rates of sodium hypochlorite leaching under microwave and low-pressure glow discharge plasmas are 66% and 72.88% respectively, while arsenic content in treated copper ore is reduced to 0.15% and 0.12% respectively, which meets arsenic index requirement of second grade copper concentrates.
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基金项目:湖北省科技支撑计划(湖北省重金属污染控制技术工程中心平台项目)(2014BEC029)
引用文本:
赵卓英,齐越,杜冬云.微波和等离子体辅助次氯酸钠浸出含砷铜矿脱砷工艺[J].有色金属(冶炼部分),2015(7):8-12.
ZHAO Zhuo-ying,QI Yue,DU Dong-yun.Arsenic Removal from Arsenic-bearing Copper Ore by Sodium Hypochlorite Leaching Assisted with Microwave and Low-pressure Glow Discharge Plasma[J].Nonferrous Metals (Extractive Metallurgy),2015(7):8-12.

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