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投稿时间：2015-01-15 修订日期：2015-01-23 录用日期：2015-01-27 网络发布日期：2015-05-20
投稿时间：2015-01-15 修订日期：2015-01-23 录用日期：2015-01-27 网络发布日期：2015-05-20
中文摘要: 采用真空感应炉对金属热还原法制备的V-Ti-Fe合金进行精炼，考察金属铈对精炼效果的影响。结果表明，铈可有效脱除合金中的氧杂质，减少合金内的富钛相和硅偏聚相，降低合金的成分偏析，促进合金的吸氢活化。随铈用量的增加，脱氧效果也逐渐增强，储氢容量得到提升，当铈添加量达到合金用量的5%时，氧含量降到了0.05%，最大吸氢量和有效放氢量分别达到3.36%和1.85%。
Abstract:V-Ti-Fe alloy prepared by metal thermal reduction was refined in vacuum induction furnace. The effect of Ce metal on refining effect was investigated. The results show that addition of Ce can effectively remove oxygen impurity in alloy, reduce componential segregation and improve hydrogen storage capacity of alloy. Deoxidization degrees and hydrogen storage capacity rise gradually with adding of Ce. When m(Ce)/m(alloy) is up to 5%, oxygen content drops to 0.05%, and the maximum hydrogen absorption capacity and effective hydrogen desorption capacity are up to 3.36% and 1.85%, respectively.
keywords: V-Ti-Fe alloy vacuum refining impurities composition segregation hydrogen storage capacity
文章编号： 中图分类号：TF703.5 文献标志码：
基金项目:国家自然科学基金资助项目（51404183）；陕西省教育厅专项（14JK1425）
| Author Name | Affiliation | |
| Wang bin | Xi’an University of Architecture and Technology | wxauat@126.com |
| Du jin-jing | ||
| Liu kui-ren | ||
| Zhu jun | ||
| Li lin-bo |
引用文本：
王斌,杜金晶,刘奎仁,朱军,李林波.V-Ti-Fe储氢合金的真空精炼[J].有色金属（冶炼部分）,2015(6):67-71.
Wang bin,Du jin-jing,Liu kui-ren,Zhu jun,Li lin-bo.Vacuum Refining of V-Ti-Fe Hydrogen Storage Alloy[J].Nonferrous Metals (Extractive Metallurgy),2015(6):67-71.
王斌,杜金晶,刘奎仁,朱军,李林波.V-Ti-Fe储氢合金的真空精炼[J].有色金属（冶炼部分）,2015(6):67-71.
Wang bin,Du jin-jing,Liu kui-ren,Zhu jun,Li lin-bo.Vacuum Refining of V-Ti-Fe Hydrogen Storage Alloy[J].Nonferrous Metals (Extractive Metallurgy),2015(6):67-71.
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