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投稿时间：2014-04-10 修订日期：2014-04-14 录用日期：2014-04-15 网络发布日期：2014-09-19
投稿时间：2014-04-10 修订日期：2014-04-14 录用日期：2014-04-15 网络发布日期：2014-09-19
中文摘要: 采用聚合硫酸铁(PFS)法处理镍钼矿酸浸液萃钼余液中的重金属离子和化学耗氧量（COD），考察双氧水用量、PFS用量、搅拌时间、pH对余液中Zn2+、Pb2+、Ni2+及COD含量的影响。结果表明，在双氧水用量20 mL/L、PFS用量60 mg/L、搅拌时间90 min、pH 11.0的条件下，COD可降至500 mg/L以下，去除率高达89%，重金属离子均达到GB 8978-1996污水综合排放一级标准。
Abstract:Heavy metal ions and chemical oxygen demand (COD) in molybdenum extraction raffinate from acidic leaching solution of Ni-Mo ores were treated by polyferric sulfate (PFS). The effects of dosage of hydrogen peroxide and PFS, stirring time and pH value on concentration of Zn2 , Pb2 , Ni2 and COD in raffinate were investigated. The results show that COD concentration can be reduced to 500 mg/L below with removal rate of 89%, and heavy metal ions meet the integrated wastewater discharge standard of GB 8978-1996 under the optimum conditions including dosage of hydrogen peroxide of 20 mL/L, PFS dosage of 60 mg/L, stirring time of 90 min and pH value of 11.0.
文章编号： 中图分类号：X703.1 文献标志码：
基金项目:国家水体污染控制与治理重大专项（2010ZX07212-008）
| 作者 | 单位 | |
| 胡磊* | 北京矿冶研究总院 | csu_huleijob@sina.cn |
| 梁新星 | 万宝矿产有限公司 | |
| 郭持皓 | 北京矿冶研究总院 | |
| 肖连生 | 中南大学冶金科学与工程学院 | |
| 曾之琪 | 中南大学冶金科学与工程学院 |
| Author Name | Affiliation | |
| HU Lei | Beijing General Research Institute of Mining and Metallurgy | csu_huleijob@sina.cn |
| LIANG Xinxing | ||
| GUO Chihao | ||
| XIAO Liansheng | ||
| ZENG Zhiqi |
引用文本：
胡磊,梁新星,郭持皓,肖连生,曾之琪.PFS法处理镍钼矿酸浸液萃钼余液的研究[J].有色金属（冶炼部分）,2014(10):40-42.
HU Lei,LIANG Xinxing,GUO Chihao,XIAO Liansheng,ZENG Zhiqi.Study of Treatment of Molybdenum Extraction Raffinate from Acidic Leaching Solution of Ni-Mo Ores by Polyferric Sulfate (PFS)[J].Nonferrous Metals (Extractive Metallurgy),2014(10):40-42.
胡磊,梁新星,郭持皓,肖连生,曾之琪.PFS法处理镍钼矿酸浸液萃钼余液的研究[J].有色金属（冶炼部分）,2014(10):40-42.
HU Lei,LIANG Xinxing,GUO Chihao,XIAO Liansheng,ZENG Zhiqi.Study of Treatment of Molybdenum Extraction Raffinate from Acidic Leaching Solution of Ni-Mo Ores by Polyferric Sulfate (PFS)[J].Nonferrous Metals (Extractive Metallurgy),2014(10):40-42.
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