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投稿时间:2013-11-01 修订日期:2013-11-04 录用日期:2013-11-05 网络发布日期:2014-04-22
投稿时间:2013-11-01 修订日期:2013-11-04 录用日期:2013-11-05 网络发布日期:2014-04-22
中文摘要: 采用硫酸熟化焙烧—酸浸工艺从失效汽车尾气催化剂中提取铈、镧,主要研究了酸料比、焙烧温度、焙烧时间、浸出温度、浸出酸度、浸出时间等对铈、镧浸出率的影响。结果表明,最佳工艺条件为:酸料比0.9,150 ℃焙烧3 h,浸出液固比4∶1,浸出硫酸浓度1.0 mol/L,浸出温度60 ℃,浸出时间4 h。此时,铈、镧的平均浸出率分别为85.80%和85.01%。
Abstract:Cerium and lanthanum were extracted from spent automobile catalyst by sulfating roasting-acid leaching. The effects of sulfuric acid consumption, roasting temperature and time, leaching temperature, acid concentration and leaching time on leaching rates of cerium and lanthanum were investigated. The results show that the leaching rate of cerium and lanthanum is 85.80% and 85.01% respectively under the optimum conditions including ratio of acid to material of 0.9, roasting temperature of 150 ℃, roasting time of 3 h, leaching ratio of liquid to solid of 4∶1, acid concentration of 1.0 mol/L, leaching temperature of 60℃, and leaching time of 4 h.
文章编号: 中图分类号:TF845 文献标志码:
基金项目:国家高技术研究发展计划(863计划)项目(2012AA063203)
| 作者 | 单位 | |
| 童伟锋 | 昆明贵金属研究所 | tong6756@163.com |
| 董海刚* | 昆明贵金属研究所 | tong6756@163.com |
| 吴晓峰 | 昆明贵金属研究所 | |
| 范兴祥 | 昆明贵金属研究所 | |
| 赵家春 | 昆明贵金属研究所 | |
| 闫君禺 | 昆明贵金属研究所 | |
| 雷云 | 昆明贵金属研究所 | |
| 李博捷 | 昆明贵金属研究所 | |
| 吴跃东 | 昆明贵金属研究所 |
引用文本:
童伟锋,董海刚,吴晓峰,范兴祥,赵家春,闫君禺,雷云,李博捷,吴跃东.从失效汽车尾气催化剂中提取铈和镧的研究[J].有色金属(冶炼部分),2014(5):42-44.
Tong Wei-feng,Dong Hai-gang,Wu Xiao-feng,Fan Xing-xiang,Zhao Jia-chun,Yan Jun-yu,Lei Yun,LI Bo-jie,Wu Yue-dong.Study on Extraction of Cerium and Lanthanum from Spent Automobile Catalyst[J].Nonferrous Metals (Extractive Metallurgy),2014(5):42-44.
童伟锋,董海刚,吴晓峰,范兴祥,赵家春,闫君禺,雷云,李博捷,吴跃东.从失效汽车尾气催化剂中提取铈和镧的研究[J].有色金属(冶炼部分),2014(5):42-44.
Tong Wei-feng,Dong Hai-gang,Wu Xiao-feng,Fan Xing-xiang,Zhao Jia-chun,Yan Jun-yu,Lei Yun,LI Bo-jie,Wu Yue-dong.Study on Extraction of Cerium and Lanthanum from Spent Automobile Catalyst[J].Nonferrous Metals (Extractive Metallurgy),2014(5):42-44.

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