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投稿时间:2013-01-18 修订日期:2013-01-21 录用日期:2013-01-22 网络发布日期:2013-07-18
投稿时间:2013-01-18 修订日期:2013-01-21 录用日期:2013-01-22 网络发布日期:2013-07-18
中文摘要: 以工业铝酸钠溶液制备的氢氧化铝为原料,采用高温固相反应法合成了Sr5Al2O7S∶Eu2 红色长余辉材料。用X射线衍射仪及荧光分光光度计对材料的物相及光谱性能进行了分析,考察稀土掺杂量对样品发光性能的影响。结果表明,在稀土激活剂的掺杂量x(Eu)=6%、硼酸加入量9%、1 200 ℃烧结8 h的条件下合成的样品为Sr5Al2O7S∶Eu2 的纯相,激发光谱位于400~500 nm,主发射波长在600 nm左右,余辉为桔红色。
中文关键词: 长余辉发光材料 Sr5Al2O7S∶Eu2 高温固相合成 发光性能 铝酸钠
Abstract:The long afterglow luminescence phosphor Sr5Al2O7S∶Eu2 was prepared by high-temperature solid-state synthesis process with aluminum hydroxide prepared from industrial sodium aluminate solution as raw material. The phase and spectra properties of the material were characterized by XRD and fluorescence spectrophotometer. The effect of Eu2 concentration on luminescent properties was investigated. The results show that under the conditions of x(Eu)=6%, x(H3BO3)=9%, and sintered at 1 200 ℃ for eight hours, the synthesized sample is composed of pure Sr5Al2O7S∶Eu2 phase, the excitation spectra locates at 400~500 nm, and the emission wavelength is about 600 nm. The afterglow of the phosphor has the color of orange.
keywords: long afterglow luminescence material Sr5Al2O7S∶Eu2 high-temperature solid-state synthesis luminescent properties aluminate
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基金项目:
| 作者 | 单位 | |
| 王红伟* | 济源职业技术学院 | mhstone@163.com |
| 王保玉 | 济源职业技术学院 | wangbaoyu@163.com |
| 马科友 | 济源职业技术学院 | mky168@163.com |
| 张学英 | 中铝公司河南分公司 |
| Author Name | Affiliation | |
| WANG Hong-wei | Jiyuan Vocational Technical college 495000 | mhstone@163.com |
| WANG Bao-yu | wangbaoyu@163.com | |
| MA Ke-you | mky168@163.com | |
| zhangxueying |
引用文本:
王红伟,王保玉,马科友,张学英.红色长余辉发光材料Sr5Al2O7S∶Eu2 的制备及发光性能[J].有色金属(冶炼部分),2013(8):53-55.
WANG Hong-wei,WANG Bao-yu,MA Ke-you,zhangxueying.Synthesis and Luminescent Properties of Red Long Afterglow Phosphor Sr5Al2O7S∶Eu2 [J].Nonferrous Metals (Extractive Metallurgy),2013(8):53-55.
王红伟,王保玉,马科友,张学英.红色长余辉发光材料Sr5Al2O7S∶Eu2 的制备及发光性能[J].有色金属(冶炼部分),2013(8):53-55.
WANG Hong-wei,WANG Bao-yu,MA Ke-you,zhangxueying.Synthesis and Luminescent Properties of Red Long Afterglow Phosphor Sr5Al2O7S∶Eu2 [J].Nonferrous Metals (Extractive Metallurgy),2013(8):53-55.

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