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有色金属(冶炼部分):2011,(5):24-26
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硫酸浓度对多孔氧化铝膜的影响
(1.东北大学;2.沈阳航空工业学院)
Effect of Sulfuric Acid Electrolyte Concentration on Porous Alumina Film
(1.Northeastern University;2.Shenyang Institute of Aeronautical Engineering)
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投稿时间:2011-02-09               
中文摘要: 在H2SO4电解液中对高纯铝箔进行阳极氧化,考察分析了电解液浓度对多孔阳极氧化铝膜的影响,结果表明:随硫酸电解液浓度的增加,纳米孔孔径逐渐增大,孔密度降低,孔的有序性先提高后降低;采用23 V直流电压进行阳极氧化,电解液浓度为0.6~1.0 mol/L时制得的氧化铝膜孔径均匀性及有序度均较好,尤其以0.8 mol/L H2SO4最佳;阳极氧化铝膜的厚度随电解液浓度的提高而增大;电解液浓度过高易于将铝箔快速击穿。
Abstract:High-pure aluminum foil was anodic oxidated in H2SO4 electrolyte. Effects of electrolyte concentration on porous alumina film were investigated. The results indicated that aperture of nano-pore increased with the increase of electrolyte concentration, and the density of nano-pore reduced with the increase of electrolyte concentration, while the order of nano-pore improved first and then deteriorated with the increase of electrolyte concentration. When aluminum foil was anodic oxidated at 23 V direct voltages, the better uniformity of aperture and order of alumina film was achieved in 0.6 ~ 1.0 mol/L electrolytes, especially in 0.8 mol/L H2SO4. The thickness of alumina film increased with the increase of electrolyte concentration. Exorbitant electrolyte concentration was prone to rapid breakdown the aluminum foil.
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王晓燕,翟秀静,张廷安,符岩,郑双.硫酸浓度对多孔氧化铝膜的影响[J].有色金属(冶炼部分),2011(5):24-26.
WANG Xiao-yan,ZHAI Xiu-jing,ZHANG Ting-an,FU Yan,ZHENG Shuang.Effect of Sulfuric Acid Electrolyte Concentration on Porous Alumina Film[J].Nonferrous Metals (Extractive Metallurgy),2011(5):24-26.

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